Recent advances in nickel-catalyzed C–C and C–N bond formation <i>via</i> HA and ADC reactions
Murugan Subaramanian, Ganesan Sivakumar, Ekambaram Balaraman
Abstract
In recent times, earth-abundant 3d-transition-metal catalysts have attracted much attention in contemporary catalysis. They have been widely employed as suitable alternatives to their counterparts noble metals. In particular, nickel catalysts provide distinctive redox properties; thus, their efficiency in sustainable organic transformations is manifold. In this review article, recent advances in nickel-catalyzed hydrogen auto-transfer (HA) and acceptorless dehydrogenative coupling (ADC) reactions for the construction of C-C and C-N bonds have been discussed.
Topics & Concepts
NickelCatalysisChemistryCombinatorial chemistryCoupling reactionOrganic chemistryAsymmetric Hydrogenation and CatalysisCatalytic C–H Functionalization MethodsChemical Reactions and Isotopes