Strong circularly polarized luminescence<i>via</i>intramolecular excited-state symmetry-breaking charge separation
Maria João Álvaro‐Martins, Chloé Billiaux, Pascale Godard, Reïko Oda, Guillaume Raffy, Dario M. Bassani
Abstract
= 0.016) both in polar and non-polar solvents that is assigned to charge separation symmetry breaking on the basis of its large transition state dipole moment (12.1 D).
Topics & Concepts
LuminescenceExcited stateIntramolecular forceDipoleCharge (physics)Symmetry breakingTransition dipole momentPolarSymmetry (geometry)Atomic physicsExcimerMolecular physicsChemistryCircular polarizationMaterials scienceCrystallographyPhysicsStereochemistryFluorescenceOpticsOptoelectronicsQuantum mechanicsOrganic chemistryMicrostripMathematicsGeometrySynthesis and Properties of Aromatic CompoundsLuminescence and Fluorescent MaterialsPhotochemistry and Electron Transfer Studies