Low carbon steel corrosion inhibition using environment-friendly Solanum Lycopersicum extract in monoprotic and diprotic acidic medium
Priya Vashishth, Bindu Mangla, Himanshi Bairagi, Rajni Narang, Sudhish Kumar Shukla
Abstract
The stem extract of Solanum Lycopersicum prepared using the methanol extraction method has been investigated as an environment-friendly inhibitor for low-carbon steel in monoprotic(1N HCl) and diprotic(1N H2SO4) solvents and characterized with FT-IR. A maximal inhibition efficiency of 81.8% in 1 N Hydrochloric acid and 92.92% in 1 N Sulfuric acid is assessed under a certain set of conditions of inhibitor concentration and temperature using weight loss, electrochemical impedance spectroscopy and potentiodynamic polarization. The results present Solanum Lycopersicum extract as a mixed-type inhibitor that predominantly influences the cathodic reaction and followed the Langmuir adsorption isotherm. Reduction in the value of average roughness (Ra)of the surface from 217 nm to 55 nm (in 1 N HCl) and 139.6 nm to 28 nm (in 1 N H2SO4) was observed with AFM after the application of the inhibitor which confirms the formation of a protective membrane and provides green inhibition on the low-carbon steel/solution interface.