B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>-catalyzed regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates
Wenjie Qin, Ni Qian, Wenjun Jiao, Yuanhong Ma
Abstract
Herein, we report a B(C 6 F 5 ) 3 -catalyzed highly regio- and stereoselective thiosulfonylation of terminal alkynes with thiosulfonates to access diverse ( E )-(β)-arylthiolvinyl sulfones.
Topics & Concepts
StereoselectivityTerminal (telecommunication)CatalysisChemistryStereochemistryAlkyneMedicinal chemistryOrganic chemistryComputer scienceTelecommunicationsSulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsOrganoselenium and organotellurium chemistry