Four-component defluorinative reaction of allylic fluorides, amidines, and Cs<sub>2</sub>CO<sub>3</sub>under transition-metal-free conditions
Yulan Chen, Li-Wen Sun, Jiawei Chen, Ming-Quan Zhu, Mengtao Ma, Zhi‐Liang Shen, Xue‐Qiang Chu
Abstract
An unprecedented four-component defluorinative reaction of allylic fluorides, amidines, and Cs 2 CO 3 for the convenient synthesis of valuable pyrimidine-containing amidino carbamates under transition-metal-free conditions was developed.
Topics & Concepts
Allylic rearrangementComponent (thermodynamics)ChemistryTransition metalMetalInorganic chemistryCatalysisMedicinal chemistryOrganic chemistryThermodynamicsPhysicsFluorine in Organic ChemistryChemical Synthesis and AnalysisCatalytic C–H Functionalization Methods