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A route towards high‐efficiency silicon heterojunction solar cells

Weiyuan Duan, Andreas Lambertz, Karsten Bittkau, Depeng Qiu, Kaifu Qiu, Uwe Rau, Kaining Ding

2021Progress in Photovoltaics Research and Applications58 citationsDOIOpen Access PDF

Abstract

Abstract In this work, we propose a route to achieve a certified efficiency of up to 24.51% for silicon heterojunction (SHJ) solar cell on a full‐size n‐type M2 monocrystalline‐silicon Cz wafer (total area, 244.53 cm 2 ) by mainly improving the design of the hydrogenated intrinsic amorphous silicon (a‐Si:H) on the rear side of the solar cell and the back reflector. A dense second intrinsic a‐Si:H layer with an optimized thickness can improve the vertical carrier transport, resulting in an improved fill factor ( FF ). In order to reduce the plasmonic absorption at the back reflector, a low‐refractive‐index magnesium fluoride (MgF 2 ) is deposited before the Ag layer; this leads to an improved gain of short circuit current density ( J sc ). In total, together with MgF 2 double antireflection coating and other fine optimizations during cell fabrication process, ~1% absolute efficiency enhancement is finally obtained. A detailed loss analysis based on Quokka3 simulation is presented to confirm the design principles, which also gives an outlook of how to improve the efficiency further.

Topics & Concepts

Materials scienceMonocrystalline siliconWaferOptoelectronicsAmorphous siliconSiliconSolar cellPolymer solar cellMagnesium fluorideFabricationReflector (photography)Crystalline siliconAbsorption (acoustics)HeterojunctionOpticsLayer (electronics)NanotechnologyComposite materialAlternative medicineLight sourcePathologyPhysicsMedicineSilicon and Solar Cell TechnologiesThin-Film Transistor Technologiessolar cell performance optimization
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