Susceptibility to intergranular corrosion in sensitized austenitic stainless steel characterized via crystallographic characteristics of grain boundaries
Tomoyuki Fujii, Masanori Suzuki, Yoshinobu SHIMAMURA
Abstract
Failures caused by intergranular corrosion have often occurred in structures made of stainless steels, and it is necessary to establish a technique to evaluate the susceptibility to such corrosion. This study investigated the crystallographic characteristics of grain boundaries to evaluate the susceptibility. To measure the characteristics, microscopic analyses were performed by the techniques of electron backscattered diffraction and thermal etching with geometric measurements. Then, oxalic acid etching was conducted. The corrosion grooves became larger with increasing grain boundary energy, and as a result, it was found that the energy was the only variable able to characterize the susceptibility.