Tunable Chemochromism and Elastic Properties in Intercalated MoO<sub>3</sub>: Au-, Cr-, Fe-, Ge-, Mn-, and Ni-MoO<sub>3</sub>
Bryan W. Reed, Ethan Chen, Kristie J. Koski
Abstract
Chemical tunability of the elastic constants of α-MoO 3, a two-dimensional layered oxide, is demonstrated with mutability on the order of tens of GPa, simply by choice of a metal intercalant including Au, Cr, Fe, Ge, Mn, and Ni. Using Brillouin laser light scattering from confined acoustic phonons in nanometer-thick materials, the in-plane angular dispersion of the quantized acoustic phonon branches of 2D layered, intercalated MoO 3 is measured and used to determine the bulk modulus ( K ), Young’s moduli ( E 11, E 22, and E 33 ), each of the nine independent elastic tensor elements ( c ij ), and the thickness. Intercalation of metals generally reduces the anisotropy in MoO 3 except in Ge-MoO 3, for which the in-plane longitudinal elastic anisotropy is unaffected. Chemochromism from transparent white (MoO 3 and Fe-MoO 3 ) to near black (Ni-MoO 3 ) to brilliant dark blue (Ge-MoO 3 ) is demonstrated and is associated with a reduction in electronic band gap with intercalation and an increase in absorption >600 nm for some intercalants (Cr-, Ge-, and Mn-MoO 3 ).