Visible light induced boryl radical and its application in reduction of unsaturated XO (X = C, N, S) bonds
Lingfeng Yin, Guanglong Huang, Xiuhua Lin, Xinluo Song, Yanqi Chen, Tianhong Yan, Ming‐De Li, Li Dang
Abstract
A boryl radical is generated by 4-cyanopyridine and B 2 cat 2 and illustrated a ketyl radical by visible light, furtherly reduced unsaturated double bond XO (X = C, N, S). The reaction mechanism is confirmed by spectroscopy and calculation studies.
Topics & Concepts
KetylChemistryVisible spectrumPhotochemistryDouble bondSpectroscopyReduction (mathematics)RadicalCrystallographyPolymer chemistryBenzophenoneOrganic chemistryOpticsPhysicsGeometryMathematicsQuantum mechanicsRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesOrganoboron and organosilicon chemistry