Heterostructures of 2D Core/Shell Nanoplatelets with 2D MoS<sub>2</sub> as an Efficient Electrocatalyst for Hydrogen Evolution Reaction
Anusri Medda, Rathindranath Biswas, Saptarshi Ghosh Dastider, Soubhik Ghosh, Krishnakanta Mondal, Krishna Kanta Haldar, Amitava Patra
Abstract
Heterostructured materials are emerging to improve the performance of hydrogen evolution reaction (HER) catalysts by controlling the interfacial charge-transfer process. Here, we report the synthesis of two-dimensional (2D) CdSe/CdS core/shell nanoplatelets (NPLs) with a 2D MoS 2 nanosheet heterostructured electrocatalyst for hydrogen generation. The phonon vibration modes E 1 2g and A 1g of pristine MoS 2 are upshifted in the case of the heterostructure due to the structural changes induced by stacking or interfacial van der Waals interactions. All of the characteristic peaks of Mo 3d are shifted to lower binding energy in the heterostructure due to the accumulation of electron density around the Mo atom. A promising electrocatalytic activity with an onset overpotential of 171 mV and a Tafel slope of 122 mV dec –1 has been obtained in 2D NPLs-based heterostructured electrocatalysts in acidic medium. Theoretical calculations reveal the creation of a sulfur defect during the HER on heterostructures, leading to excellent activity due to the optimum adsorption of the H* intermediate in the hydrogen-evolving reaction.