Bright Red Luminescence from Ag–In–Ga–S-Based Quantum Dots with the Introduction of Copper
Taro Uematsu, Navapat Krobkrong, Kenichiro Asai, Genichi Motomura, Yoshihide Fujisaki, Tsukasa Torimoto, Susumu Kuwabata
Abstract
Abstract This study presents cadmium-free, red-emission quantum dots (QDs) synthesized by incorporating Cu into silver indium gallium sulfide/gallium sulfide (Ag–In–Ga–S/Ga–S) core/shell QDs. By using a previous technique, in which the original Ag–In–Ga–S/Ga–S core/shell QDs exhibiting band-edge photoluminescence (PL) were improved to achieve a narrower emission and facile synthesis, we injected a mixture of Cu and Ag sources into a heated solution containing In, Ga, and S sources. This resulted in the formation of Ag–Cu–In–Ga–S quinary QDs without any precipitation. After being coated with a Ga–S shell, these QDs exhibit a red PL with a spectral full-width at half maximum of 55–60 nm. Although the PL wavelength was responsive to changes in In/Ga ratios, it was unaffected by variations in Cu/Ag ratios due to the transition between conduction band electrons and holes localized at Cu cites. Notably, the electroluminescence device exhibited high-purity red light that satisfies the recommendation ITU-R BT.2020 standard.