Synergy of activating substrate and introducing C-H···O interaction to achieve Rh2(II)-catalyzed asymmetric cycloisomerization of 1,n-enynes
Rui Wu, Kai Chen, Jun Ma, Zhi‐Xiang Yu, Shifa Zhu
Topics & Concepts
CycloisomerizationCatalysisCyclopropanationSubstrate (aquarium)ChemistryDensity functional theoryEnyneAlkyneTetraStereochemistryMedicinal chemistryComputational chemistryOrganic chemistryBiologyEcologyCyclopropane Reaction MechanismsCatalytic Alkyne ReactionsCatalytic C–H Functionalization Methods