Impermeable Graphene Skin Increases the Heating Efficiency and Stability of an MXene Heating Element
Dong Jun Kang, Ki Hyun Lee, Sung Hyun Noh, Hwansoo Shin, Woojae Jeong, Hyeonhoo Lee, Yeongbhin Seo, Tae Hee Han
Abstract
Abstract A Joule heater made of emerging 2D nanosheets, i.e., MXene, has the advantage of low‐voltage operation with stable heat generation owing to its highly conductive and uniformly layered structure. However, the self‐heated MXene sheets easily get oxidized in warm and moist environments, which limits their intrinsic heating efficiencies. Herein, an ultrathin graphene skin is introduced as a surface‐regulative coating on MXene to enhance its oxidative stability and Joule heating efficiency. The skin layer is deposited on MXene using a scalable solution‐phased layer‐by‐layer assembly process without deteriorating the excellent electrical conductivity of the MXene. The graphene skin comprises narrow and hydrophobic channels, which results in ≈70 times higher water impermeability of the hybrid film of graphene and MXene (GMX) than that of the pristine MXene. A complementary electrochemical analysis confirms that the graphene skin facilitates longer‐lasting protection than conventional polymer coatings owing to its tortuous pathways. In addition, the sp 2 planar carbon surface with a low heat loss coefficient improves the heating efficiency of the GMX, indicating that this strategy is promising for developing adaptive heating materials with a tractable voltage range and high Joule heating efficiency.