High Fluorescence Rate of Thermally Activated Delayed Fluorescence Emitters for Efficient and Stable Blue OLEDs
Liwu Su, Fangyi Cao, Cong Cheng, Taijū Tsuboi, Yunhui Zhu, Chao Deng, Xinyuan Zheng, Dan Wang, Zhang Liu, Qisheng Zhang
Abstract
A lack of an efficient and stable blue device is a critical factor restricting the development of organic light-emitting diode (OLED) technology that is currently expected to be overcome by employing thermally activated delayed fluorescence (TADF). Here, we investigate the TADF and electroluminescence (EL) performance of six carbazole/triphenyltriazine derivatives in different hosts. A good linearity between lg(LT50/kF2) and the EL emission wavelength is found, where LT50 is the half-life of the devices and kF is the fluorescence rate of the emitters, suggesting the dominance of the singlet exciton energy and lifetime in device stability. An indolylcarbazole/triphenyltriazine derivative (ICz-TRZ) with the capability to suppress solid-state solvation exhibits blue-shifted emission and an increased kF (1.5 × 108 s–1) in comparison to the control emitters in doped films. ICz-TRZ-based devices achieve a maximum external quantum efficiency (EQE) of 18% and an EQE of 5.5% at a very high luminance of 7 × 104 cd/m2. Ignoring the poor electrochemical stability of ICz-TRZ, the device offers an LT50 approaching 100 h under an initial luminance of 1000 cd/m2 and CIE coordinates of (0.14, 0.19). The findings in this work suggest that computer-aided design of high kF TADF emitters can be an approach to realize efficient and stable blue OLEDs.