Ligand-controlled cobalt-catalyzed regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes
Caizhi Wu, Shaozhong Ge
Abstract
The first cobalt-catalyzed stereoselective regiodivergent hydroboration of internal allenes to access synthetically versatile (<italic>Z</italic>)-alkenylboronate compounds was effectively achieved with two cobalt catalysts through ligand control.
Topics & Concepts
HydroborationAlkylLigand (biochemistry)ChemistryCobaltArylCatalysisStereochemistryOrganic chemistryBiochemistryReceptorOrganoboron and organosilicon chemistryCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization Methods