RbPbPS<sub>4</sub>: a promising IR nonlinear optical material achieved by lone-pair-cation-substitution-induced structure transformation
A-Yang Wang, Shenghua Zhou, Mao‐Yin Ran, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu
Abstract
A novel excellent IR-NLO material RbPbPS 4 with superior comprehensive performances is provided, representing the first quaternary Pb-based chalcogenide breaks through the incompatibility between a large E g and a strong d eff .
Topics & Concepts
ChalcogenideSubstitution (logic)Lone pairNonlinear opticalTransformation (genetics)Materials scienceCrystallographyChemistryNonlinear systemMoleculeOptoelectronicsOrganic chemistryComputer sciencePhysicsQuantum mechanicsBiochemistryProgramming languageGeneCrystal Structures and PropertiesSolid-state spectroscopy and crystallographyNonlinear Optical Materials Research