Competitive Site Occupation toward Improved Quantum Efficiency of SrLaScO<sub>4</sub>:Eu Red Phosphors for Warm White LEDs
Zhiyu Yang, Gaochao Liu, Yifei Zhao, Yayun Zhou, Jianwei Qiao, Мaxim S. Моlokeev, H.C. Swart, Zhiguo Xia
Abstract
Abstract The discovery of Eu 2+ ‐doped high‐efficiency red phosphors remains a vital challenge for white light‐emitting diode (WLED) applications. It is therefore urgent to find effective strategies managing the oxidation state to help reduce Eu 3+ to Eu 2+ and accordingly increase the photoluminescence quantum yield (PLQY). Herein, a new red‐emitting SrLaScO 4 :Eu phosphor is designed, and the PLQY is enhanced from 13% to 67% under 450 nm excitation by employing (NH 4 ) 2 SO 4 ‐assisted sintering. Combined structural analysis, optical spectroscopy, and theoretical calculation reveal that predominant Eu 2+ prefers to occupy the Sr 2+ sites in the SrLaScO 4 enabling red emission, and a competitive site occupation of Eu 3+ in La 3+ can be restrained, and the reduction mechanism of Eu 3+ to Eu 2+ originating from the (NH 4 ) 2 SO 4 addition is analyzed. The fabricated WLED device using red‐emitting SrLaScO 4 :Eu and yellow‐emitting Y 3 (Al,Ga) 5 O 12 :Ce 3+ exhibits a high color‐rendering index of 86.7 at a low correlated color temperature of 4005 K. This work provides a feasible reduction strategy for guiding the development of high‐efficiency Eu 2+ ‐doped red phosphor for WLED applications.