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Modelling and Performance Analysis of Physical and Electrical Properties of BaZrS3 Chalcogenide Perovskite Solar Cells

Devansh Gahlawat, Jaspinder Kaur, Rikmantra Basu, Ajay Kumar Sharma, Uma Rani

202411 citationsDOI

Abstract

This study explores the application and utility of BaZrS3-based perovskite solar cells (PSCs) for thin-film photovoltaic applications. The proposed device exhibited stable current up to 1.1 eV and maintained over 65% quantum efficiency across a broad spectrum. The Mott-Schottky analysis indicated a bandgap of approximately 1.7 eV. Nyquist and Bode plots confirmed robust impedance behaviour. The device displayed <tex xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">$\mathbf{V}_{\text{oc}}=1.33\ \mathrm{V}, \mathbf{J}_{\mathbf{sc}}$</tex> = 16.56 mA/cm2, FF = 83.97%, and Efficiency = 18.58%. BaZrS3's exceptional optical and electrical properties, coupled with environmental stability, position it as a promising material for advanced PSCs.

Topics & Concepts

ChalcogenidePerovskite (structure)Materials scienceOptoelectronicsEngineering physicsElectronic engineeringComputer scienceChemical engineeringPhysicsEngineeringPerovskite Materials and ApplicationsChalcogenide Semiconductor Thin Films
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