Practical copper-catalyzed chloronitration of alkenes with TMSCl and guanidine nitrate
Si‐Yuan Li, Zhen‐Yu Guan, Jing Xue, Guangyi Zhang, Xiao-Yu Guan, Qing‐Hai Deng
Abstract
A practical chloronitration of alkenes catalyzed by cheap copper sulfate pentahydrate to provide<italic>vic</italic>-chloronitro compounds in good to excellent yields was developed, and the resulting products could be transformed into diverse nitro compounds.
Topics & Concepts
ChemistryGuanidineCopperCatalysisNitrateCopper sulfateOrganic chemistrySilver nitrateCombinatorial chemistryChemical Synthesis and ReactionsCatalytic C–H Functionalization MethodsSynthesis and Catalytic Reactions