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Structures and impact strength variation of chemically crosslinked high-density polyethylene: effect of crosslinking density

Yueqing Ren, Xiaojie Sun, Lanlan Chen, Yafei Li, Miaomiao Sun, Xuelei Duan, Wenbin Liang

2021RSC Advances72 citationsDOIOpen Access PDF

Abstract

and 360% respectively. With increase in crosslink agent, the flexural modulus, yield strength, crystallinity, mean lamellar thickness, crystal size and spherulitic size and the brittle-ductile transition temperature (BDTT) decrease, and the gel content, impact strength of the HDPE at low temperature, intensity of β transition increase significantly. In considering both the room temperature mechanical properties and low temperature impact strength, the optimized content of the crosslink agent is about 0.7%. Overall, crosslinking significantly improves the toughness and impact strength of HDPE and extends its application, especially at low temperature.

Topics & Concepts

Variation (astronomy)PolyethyleneHigh-density polyethyleneMaterials sciencePolymer chemistryIzod impact strength testComposite materialChemical engineeringUltimate tensile strengthAstrophysicsEngineeringPhysicsPolymer crystallization and propertiesPolymer Nanocomposites and PropertiesStructural Behavior of Reinforced Concrete