Fluorescence sensor enabled control of contaminants of emerging concern in reclaimed wastewater using ozone-based treatment processes
Luigi Marino, Erica Gagliano, Domenico Santoro, Paolo Roccaro
Abstract
• Fluorescence sensor signals correlate with changes in water quality due to AOPs • Online monitoring of micropollutants during O 3 -based AOPs by fluorescence sensor • Real-time fluorescence signals of AOP effluent can monitor ozone dose • Online fluorescence sensor signals can predict the CEC degradation rate constants Contaminants of emerging concern (CEC) pose significant challenges to environmental and human health. The development of the wastewater reuse sector, coupled with progressively stringent regulations, needs innovative systems that integrate advanced treatment processes with in-situ and real-time monitoring of CEC. This study investigates the use of a tryptophan-like fluorescence sensor for real-time and online monitoring of CEC within a pilot plant employing O 3 -based advanced oxidation processes (AOPs). Two tertiary wastewater effluents (WW-1 and WW-2) were tested, placing the pilot system downstream of two different wastewater treatment plants (WWTPs). Priority substances and micropollutants detected in the investigated water matrixes such as pharmaceuticals, per- and polyfluoroalkyl substances (PFAS) were selected as targeted compounds in this study. Fluorescence degradation was detected in real-time by the sensor, showing a high capability to detect fast changes in water quality induced by oxidation. Furthermore, the real-time fluorescence showed better sensitivity than lab-scale fluorescence in detecting the fast action of hydroxyl radicals (•OH) during the O 3 /H 2 O 2 process, highlighting the importance of online monitoring. Selected CEC were degraded by AOPs with different percentages of removal efficiency (RE) ( 0 % < RE < 100 % in WW-1 and 15 % < RE < 90 % in WW-2) depending on oxidant doses and the reactivity of compounds with O 3 and •OH. Fluorescence data by online sensor enabled accurate prediction of the removal of a wide spectrum of CEC during O 3 and O 3 /H 2 O 2 processes ( R 2 ≥ 0.93 ). Furthermore, real-time fluorescence data were successfully used to predict observed pseudo-first-order rate constants of CEC with O 3 or O 3 /H 2 O 2 . Obtained results suggest that real-time fluorescence monitoring is an excellent tool to control CEC removal during O 3 -based AOPs and monitor the transferred ozone in wastewater ( R 2 ≥ 0.94 ), contributing to the optimization of reagent dose, energy and costs.