Comparative Study of TiO<sub>2</sub> and CdS as the Electron Transport Layer for Sb<sub>2</sub>S<sub>3</sub> Solar Cells
Yiyu Zeng, Jialiang Huang, Jianjun Li, Kaiwen Sun, Usman Ali Shah, Hui Deng, Xueyun Zhang, Chuhan Sha, Chen Qian, Haisheng Song, Xiaojing Hao
Abstract
Antimony sulfide (Sb 2 S 3 ) is a promising wide‐bandgap photovoltaic material, and a potential top‐cell candidate for next‐generation Si‐based tandem solar cells. The most widely used electron transport layers in Sb 2 S 3 solar cells are TiO 2 and CdS, which present an obvious performance variation in open‐circuit voltage ( V OC ) and short current ( J sc ). However, the mechanisms behind the performance disparity because of the electron transport layer (ETL) have not been disclosed. Herein, a comprehensive comparative study of using TiO 2 and CdS as the electron transport layers in Sb 2 S 3 solar cells is presented, which covers their influence on preferential crystal orientation, band alignment, interface, and bulk defects. It is found that the CdS ETL results in less interfacial defects and more favorable band alignment, enabling a higher V OC , while the high resistance of the CdS film and parasitic light absorption restricts the J SC . The findings provide a substantial guidance on device optimization for Sb 2 S 3 solar cells.