Amino-assisted synthesis of alkynylthioethers <i>via</i> a visible-light-induced C<sub>(sp)</sub>–S<sup>II</sup> coupling between bromoalkynes and 2,2′-diaminodiaryldisulfides
Ruyi Ye, Hongjie Ruan, Hailong Xu, Ziyang Li, Ling‐Guo Meng, Lei Wang
Abstract
A straightforward synthesis of alkynylthioethers via amino-assisted/visible-light-promoted coupling of bromoalkynes with 2,2′-diaminodiaryldisulfides without transition metals, photocatalysts and additives was developed.
Topics & Concepts
ChemistryCoupling (piping)Visible spectrumTransition metalAmino acidPhotochemistryCombinatorial chemistryOptoelectronicsOrganic chemistryCatalysisPhysicsBiochemistryMetallurgyMaterials scienceSulfur-Based Synthesis TechniquesRadical Photochemical ReactionsCyberloafing and Workplace Behavior