Thermal N–O bond heterolysis of TEMPO-CF<sub>2</sub>CF<sub>3</sub> towards trifluoroacetylation of alcohols and amines
Tao Dong, Yihan Tang, Gavin Chit Tsui
Abstract
A perfluoroalkoxyamine TEMPO-CF 2 CF 3 can be synthesized on gram-scale and it undergoes unusual N–O bond heterolytic cleavage under thermal conditions.
Topics & Concepts
HeterolysisChemistryMedicinal chemistryOrganic chemistryCatalysisFluorine in Organic ChemistryInorganic Fluorides and Related CompoundsCarbon dioxide utilization in catalysis