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Spatial and temporal heterogeneity of Kohlrausch–Williams–Watts stress relaxations in metallic glasses

Akio Ishii

2021Computational Materials Science15 citationsDOIOpen Access PDF

Abstract

We perform a molecular dynamics (MD) stress relaxation simulation for Zr50Cu40Al10 metallic glass to confirm that the time dependency of stress relaxation conforms with the Kohlrausch–Williams–Watts (KWW) equation, and to derive the temperature dependency of the Kohlrausch exponent βKWW. We also calculate local plastic deformation based on atomic strain, then discuss the morphology of relaxation and calculate the probability density of stress relaxation with respect to the characteristic time of relaxation from the number of deformed atoms. Afterward, we derive the time dependency of stress relaxation as a mode-averaged decay function, which expresses spatial and temporal heterogeneity. Both the results of simulation and calculation reproduce the KWW relaxation form and are in good agreement, confirming the spatially and temporally heterogeneous nature of KWW relaxation. The heterogeneity of the stress relaxation of metallic glass is determined by local stress changes caused by microscopic local plastic deformation.

Topics & Concepts

Relaxation (psychology)Stress relaxationStress (linguistics)ExponentMaterials scienceDeformation (meteorology)Amorphous metalCondensed matter physicsPhysicsComposite materialCreepLinguisticsSocial psychologyAlloyPsychologyPhilosophyMetallic Glasses and Amorphous AlloysMaterial Dynamics and PropertiesGlass properties and applications