Radical-induced single-molecule conductance tuning in 9,9′-bifluorenylidene derivatives
Hanjun Zhang, Lichuan Chen, Yunzhu Huang, Xiaodong Liu, Sergio Moles Quintero, Wenjing Hong, Dongsheng Wang, Juan Casado, Yonghao Zheng
Abstract
represents the diradical index), the influence of organic radical spin delocalization on the conducting path can be gradually modulated, transforming linear conjugated conducting channels into cross-conjugated channels and significantly reducing single-molecule conductance. This discovery provides an in-depth understanding of the complex relationship between radicals, spin delocalization, and molecular conductance, which is rather unique in the area of functional stable radical compounds. Ultimately, it provides forward-looking guidance for research on these materials in the field of organic electronic materials.