A novel approach to design sustainable fiber reinforced materials from renewable sources: mathematical modeling for the evaluation of the effect of fiber content on biocomposite properties
Gianluca Viscusi, Giuliana Gorrasi
Abstract
The paper reports a sustainable, fast and efficient methodology to treat natural hemp fibers (HF) using a mechanochemical approach. Mechanical milling was used to carry out an alkaline attack on HFs for 30 min at ambient temperature. Composites HF/pectins were prepared by varying the fiber weight fraction (3%; 7.5%; 10%; 20% w/w by weight). The improvement in thermal degradation, mechanical and barrier properties to water vapor was correlated with the fiber volume fraction and mainly due to the improved fiber-matrix adhesion. The fibers–matrix interaction was then evaluated by analyzing and modeling the mechanical properties using several mathematical models: a modified Nielsen and Pukànszky and Smith models. Sorption isotherms to water vapor were analyzed through a modified Guggenheim, Anderson, de Boer (GAB) model where a new parameter, α, was introduced to consider the heterogeneity of the system. Finally, a modified Burgemman model was used to fit the experimental data and support the improvement in water diffusion with fiber loading.