Low temperature‐synthesized MgAl<sub>2</sub>O<sub>4</sub>:Eu<sup>3+</sup> nanophosphors and their structural validations using density functional theory: photoluminescence, photocatalytic, and electrochemical properties for multifunctional applications
Santhepete Nanjundaiah Manjula, M. Chandrasekhar, Ramachandra Naik, V. Revathi, H. Nagabhushana, C.R. Ravikumar, B.S. Surendra, Naveen kumar A.
Abstract
Abstract A low temperature‐assisted and oxalyl dihydrazide fuel‐induced combustion synthesized series of uncalcined MgAl 2 O 4 :Eu 3+ nanophosphors showed an average crystallite size of ~20 nm, and bandgap energy (E g ) of 4.50–5.15 eV, and were validated using density functional theory and found to match closely with the experimental values. The photoluminescence characteristic emission peaks of Eu 3+ ions were recorded between 480 and 680 nm. The nanophosphors excited at 392 nm showed f–f transitions assigned as 5 D 0 → 7 F J (J = 0, 1, 2, and 3). The optimized MgAl 2 O 4 phosphors had Commission Internationale de l'Eclairage coordinates in the red region, a correlated colour temperature of 2060 K, and a colour purity of 98.83%. The estimated luminescence quantum efficiency ( ) was observed to be ~63% using Judd–Ofelt analysis. Electrochemical and photocatalytic performance were explored and indicated its multifunctional applications. Therefore, MgAl 2 O 4 :Eu 3+ nanophosphors could be used for the fabrication of light‐emitting diodes, industrial dye degradation, and as electrodes for supercapacitor applications.