Porphyrin-based porous organic polymers synthesized using the Alder–Longo method: the most traditional synthetic strategy with exceptional capacity
Qian Liu, Wen Pan, Junshan Zhang, Mei Yang, Qin Chen, Feng Liu, Juan Li, Songrui Wei, Guoji Zhu
Abstract
the cyclic tetramerization of pyrrole with monomers containing multiple aldehyde groups during the polymerization process. The representative applications of porphyrin-based POPs derived using the Alder-Longo method are finally introduced, which pinpoints a clear relationship between the structure and function from the aspect of the building blocks used and porous structures. This review is therefore valuable for the rational design of efficient porphyrin-based porous organic polymer systems that may be utilized in various fields from energy-related conversion/storage technologies to biomedical science.
Topics & Concepts
AlderDiels–Alder reactionPorphyrinOrganic polymerPolymerPorosityPolymer scienceMaterials scienceChemical engineeringChemistryOrganic chemistryEngineeringBotanyCatalysisBiologyCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsPorphyrin and Phthalocyanine Chemistry