The stereo-divergent functionalization of alkynes: a comprehensive review
Ranjay Shaw, Ashmita Singh, Ismail Althagafi, Ramendra Pratap, Dharmendra Kumar Yadav
Abstract
-selectivity using innovative catalysts like cobalt, nickel, and palladium through hydrogenation, hydroboration, and hydrosilylation. Recent breakthroughs such as dual-catalytic systems and energy transfer catalysis enable unprecedented stereocontrol. Sustainable strategies including water as a hydrogen source and recyclable catalysts align with green chemistry principles, paving the way for eco-friendly synthesis. This synthesis of cutting-edge techniques and their applications inspire new avenues in synthetic chemistry, offering transformative tools for creating complex molecular architectures with precision and sustainability.
Topics & Concepts
Surface modificationDivergent synthesisCombinatorial chemistryComputer scienceChemistryOrganic chemistryCatalysisPhysical chemistryAsymmetric Synthesis and CatalysisOrganoboron and organosilicon chemistryCatalytic C–H Functionalization Methods