Bicyclic (alkyl)(amino)carbene (BICAAC) in a dual role: activation of primary amides and CO<sub>2</sub>towards catalytic<i>N</i>-methylation
Nimisha Gautam, Ratan Logdi, P Sreejyothi, Antara Roy, Ashwani K. Tiwari, Swadhin K. Mandal
Abstract
for a few biologically important molecules. A detailed study of the mechanism was carried out with the help of spectroscopic studies and DFT calculations.
Topics & Concepts
Bicyclic moleculeCarbeneChemistryAlkylCatalysisPrimary (astronomy)AmideCombinatorial chemistryMoleculeMethylationStereochemistryOrganic chemistryBiochemistryAstronomyPhysicsGeneCarbon dioxide utilization in catalysisAsymmetric Hydrogenation and CatalysisOrganoboron and organosilicon chemistry