A novel heterogeneous catalyst NH<sub>2</sub>-MIL-88/PMo<sub>10</sub>V<sub>2</sub> for the photocatalytic activity enhancement of benzene hydroxylation
Panpan Xu, Liuxue Zhang, Xu Jia, Hao Wen, Xiulian Wang, Suqing Yang, Juxian Hui
Abstract
In this work, heterogeneous catalyst NH 2 -MIL-88/PMo 10 V 2 -3 has shown the high hydroxylation activity of benzene under visible light (a 5 W LED), which mainly attributed to the production of hydroxyl radical(˙OH) and V 5+ /V 4+ redox pair in the existence of electron (e − ).
Topics & Concepts
HydroxylationCatalysisBenzenePhotocatalysisChemistryRedoxHeterogeneous catalysisHydroxyl radicalPhotochemistryInorganic chemistryMedicinal chemistryOrganic chemistryRadicalEnzymeAdvanced Photocatalysis TechniquesPolyoxometalates: Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis