Tuning the Diradical Character of Indolocarbazoles: Impact of Structural Isomerism and Substitution Position
Irene Badía‐Domínguez, Sofia Canola, V. Hernández, Juan T. López Navarrete, J. C. Sancho-Garcı́a, Fabrizia Negri, M. Carmen Ruiz Delgado
Abstract
-substituted systems with a V-shaped structure displaying the largest diradical character. Thus, this work contributes to the elucidation of the challenging chemical reactivity and physical properties of diradicaloid systems, guiding experimental chemists to produce new molecules with desirable properties.
Topics & Concepts
DiradicalSubstitution (logic)Character (mathematics)Position (finance)ChemistryComputer scienceEconomicsMathematicsPhysicsFinanceGeometryExcited stateProgramming languageNuclear physicsSinglet stateSynthesis and Properties of Aromatic CompoundsAxial and Atropisomeric Chirality SynthesisPhotochromic and Fluorescence Chemistry