Thermodynamics Drives the Stability of the MOF-74 Family in Water
Albert A. Voskanyan, Vitaliy G. Goncharov, Novendra Novendra, Xiaofeng Guo, Alexandra Navrotsky
Abstract
O under ambient conditions. Thus, these differences in reactivity with water are thermodynamically controlled and energetics of formation, either measured or predicted, can be used to assess the extent of water sensitivity for different possible MOFs.
Topics & Concepts
Endothermic processExothermic reactionMetal-organic frameworkChemistryHydrolysisStandard enthalpy of formationCalorimetryImidazolateIsothermal titration calorimetryChemical engineeringInorganic chemistryEnthalpyAdsorptionThermodynamicsPhysical chemistryOrganic chemistryPhysicsEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsEnergetic Materials and CombustionZeolite Catalysis and Synthesis