Dichotomy of π-stacking-directing noncovalent forces in organic–inorganic planar assemblies: the case of halo-substituted benzoquinones π-stacked with a platinum(<scp>ii</scp>) square-plane
Eugene A. Katlenok, Anton V. Rozhkov, Maxim L. Kuznetsov, Vitalii V. Suslonov, Vadim Yu. Kukushkin
Abstract
The same organic–inorganic π-stacked structures of tetrahalo-1,4-benzoquinones QX (X = F, Cl, Br, I) with different interplanar holding forces have been investigated.
Topics & Concepts
StackingPlatinumSquare (algebra)PlanarNon-covalent interactionsHaloMaterials scienceNanotechnologyCrystallographyChemistryPhysicsMoleculeGeometryMathematicsComputer scienceOrganic chemistryHydrogen bondQuantum mechanicsCatalysisComputer graphics (images)GalaxyCrystallography and molecular interactionsSupramolecular Chemistry and ComplexesSynthesis and Properties of Aromatic Compounds