Ligand and solvent effects on CO<sub>2</sub> insertion into group 10 metal alkyl bonds
Anthony P. Deziel, Matthew R. Espinosa, Ljiljana Pavlovic, David J. Charboneau, Nilay Hazari, Kathrin H. Hopmann, Brandon Q. Mercado
Abstract
2 mechanism and we compare the reaction pathway for carbon dioxide insertion into group 10 methyl complexes with insertion into group 10 hydrides. Overall, this work provides fundamental insight that will be valuable for the development of improved and new catalysts for carbon dioxide utilization.
Topics & Concepts
ChemistryInsertion reactionAlkylLigand (biochemistry)Migratory insertionCarbon dioxideMetalMedicinal chemistryMain group elementTransition metalSolventStereochemistryPolymer chemistryCatalysisOrganic chemistryReceptorBiochemistryCarbon dioxide utilization in catalysisCO2 Reduction Techniques and CatalystsOrganoboron and organosilicon chemistry