Ambient synthesis of metal–covalent organic frameworks with Fe-iminopyridine linkages
Tiantian Feng, Bing Sun, Qing Hao, Jing Li, Ying Xu, Hong Shang, Dong Wang
Abstract
Highly crystalline Fe-COFs were constructed from the building blocks carrying pyridyl-aldehyde and triamine moieties in the presence of Fe(OTf) 2 and acetic acid under ambient conditions via a subcomponent assembly strategy.
Topics & Concepts
Covalent bondAldehydeMetalChemistryAcetic acidMetal ions in aqueous solutionIonNitrogenCombinatorial chemistryPolymer chemistryPhotochemistryOrganic chemistryCatalysisCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent Materials