Fabricating Dual‐Atom Iron Catalysts for Efficient Oxygen Evolution Reaction: A Heteroatom Modulator Approach
Yong‐Sheng Wei, Liming Sun, Miao Wang, Jinhua Hong, Lianli Zou, Hong‐Wen Liu, Yu Wang, Mei Zhang, Zheng Liu, Yinwei Li, Satoshi Horike, Kazu Suenaga, Qiang Xü
Abstract
Abstract Understanding the thermal aggregation behavior of metal atoms is important for the synthesis of supported metal clusters. Here, derived from a metal–organic framework encapsulating a trinuclear Fe III 2 Fe II complex (denoted as Fe 3 ) within the channels, a well‐defined nitrogen‐doped carbon layer is fabricated as an ideal support for stabilizing the generated iron nanoclusters. Atomic replacement of Fe II by other metal(II) ions (e.g., Zn II /Co II ) via synthesizing isostructural trinuclear‐complex precursors (Fe 2 Zn/Fe 2 Co), namely the “heteroatom modulator approach”, is inhibiting the aggregation of Fe atoms toward nanoclusters with formation of a stable iron dimer in an optimal metal–nitrogen moiety, clearly identified by direct transmission electron microscopy and X‐ray absorption fine structure analysis. The supported iron dimer, serving as cooperative metal–metal site, acts as efficient oxygen evolution catalyst. Our findings offer an atomic insight to guide the future design of ultrasmall metal clusters bearing outstanding catalytic capabilities.