Insulated π-conjugated 2,2′-bipyridine transition-metal complexes: enhanced photoproperties in luminescence and catalysis
Tomohiro Iwai, Shinsuke Abe, Shin‐ya Takizawa, Hiroshi Masai, Jun Terao
Abstract
-phenylene ethynylene). The insulated π-conjugated 2,2'-bipyridine exhibited enhanced ligand performance in the solid-state emitting biscyclometalated Ir complexes and visible-light-driven Ni catalysts owing to π-extension and remote steric effects based on the linked rotaxane structure.
Topics & Concepts
Conjugated systemLuminescenceTransition metalCatalysisBipyridinePhotochemistryChemistryMetalMaterials scienceCombinatorial chemistryPolymer chemistryOrganic chemistryPolymerOptoelectronicsCrystal structureRadical Photochemical ReactionsLuminescence and Fluorescent MaterialsOrganic Light-Emitting Diodes Research