Promoting SO<sub>4</sub><sup>·–</sup> and <sup>·</sup>OH Generation from Sulfate Solution toward Efficient Electrochemical Oxidation of Organic Contaminants at a B/N-Doped Diamond Flow-Through Electrode
Genwang Zhu, Haolei Yang, Xinfei Fan, Xie Quan, Yanming Liu
Abstract
Electrochemical oxidation via in situ-generated reactive oxygen species (ROS) is effective for the mineralization of refractory organic pollutants. However, the oxidation performance is usually limited by the low yield and utilization efficiency of ROS. Herein, a B/N-doped diamond (BND) flow-through electrode with enhanced SO 4 ·– / · OH generation and utilization was designed for electrochemical oxidation of organic pollutants in sulfate solution. Both its SO 4 ·– / · OH yields and SO 4 ·– selectivity were improved by regulating B/N doping, and the production and utilization of SO 4 ·– / · OH were facilitated by flow-through mode. BND showed fast PFOA oxidation with kinetic constants of 2.56–4.58 h –1 at low current densities of 2.0–5.0 mA cm –2 . Its energy consumption for PFOA oxidation was 2.15–6.46 kWh m –3, which was lower than those of state-of-the-art electrodes under similar conditions. The BND anode was also efficient for treating organic fluorine wastewater and coking wastewater. The superior performance was contributed by its enhanced SO 4 ·– / · OH yields and utilization, as well as high SO 4 ·– selectivity.