Litcius/Paper detail

New Insights in the Production of Simulated Moon Agglutinates: the Use of Natural Zeolite-Bearing Rocks

Maela Manzoli, Olimpia Tammaro, Antonello Marocco, Barbara Bonelli, Gabriele Barrera, Paola Tiberto, Paolo Allia, Jean-Charles Matéo‐Vélez, Aurélien Roggero, Éric Dantras, Rossella Arletti, Michele Pansini, Serena Esposito

2021ACS Earth and Space Chemistry12 citationsDOIOpen Access PDF

Abstract

Two natural zeolite-bearing rocks (one containing clinoptilolite and the other chabazite, phillipsite, and analcime) were Fe-exchanged and thermally treated in a reducing atmosphere at 750 °C for 2 h. Two nanocomposites, formed by the dispersion of Fe nanoparticles in a ceramic matrix, were obtained. The prepared lunar dust simulants also contain Na+, K+, Ca2+, and Mg2+ and other mineral phases originally present in the starting materials. The samples were fully characterized by different techniques such as atomic absorption spectrometry, X-ray powder diffraction, followed by Rietveld analysis, transmission electron microscopy, N2 adsorption/desorption analysis at 77 K, measurements of grain size distribution, magnetic property measurements, broad-band dielectric spectroscopy, and DC conductivity measurements. The results of this characterization showed that the obtained metal–ceramic nanocomposites exhibit a chemical and mineralogical composition and electrical and magnetic properties similar to real moon dust and, thus, appear valid moon dust simulants.

Topics & Concepts

ClinoptiloliteZeoliteMaterials scienceChabaziteCeramicMineralogyNanocompositeAnalytical Chemistry (journal)Rietveld refinementAnalcimeDispersion (optics)Chemical engineeringChemistryComposite materialCrystallographyCrystal structureEnvironmental chemistryCatalysisEngineeringBiochemistryPhysicsOpticsPlanetary Science and ExplorationAstro and Planetary ScienceClay minerals and soil interactions