Direct and efficient synthesis of tetrasubstituted allenyl organothiophosphates from propargylic alcohols under catalyst- and additive-free conditions
Yuxing Zhang, Sha Du, Tao Yang, Fengyan Jin, Jingyi Zhou, Banpeng Cao, Zhijie Mao, Xian‐Rong Song, Qiang Xiao
Abstract
An environment-friendly approach that affords tetrasubstituted allenyl organothiophosphates from easily prepared propargylic alcohols and phosphorothioic acids [(RO) 2 P(O)SH] with water as the only by-product is developed.
Topics & Concepts
ChemistryCatalysisCombinatorial chemistryOrganic chemistryCatalytic Alkyne ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods