Electrochemical Hydrosilylation of Alkynes
Tony Biremond, Philippe Jubault, Thomas Poisson
Abstract
Si-Bpin), a large panel of terminal alkynes and internal alkynes was successfully converted into the hydrosilylated product in good to excellent yields and good selectivity in favor of the linear product. Preliminary mechanistic study supported the involvement of a silyl radical, which reacted on the alkyne.
Topics & Concepts
HydrosilylationAlkyneReagentElectrochemistrySilylationChemistrySelectivityCombinatorial chemistryOrganic chemistryPolymer chemistryElectrodeCatalysisPhysical chemistryRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods