Photo/Ni dual-catalyzed radical defluorinative sulfonylation to synthesize<i>gem</i>-difluoro allylsulfones
Yiran Xu, Shengchun Wang, Zhao Liu, Mian Guo, Aiwen Lei
Abstract
-difluoro allylsulfones. The merit of this protocol is exhibited by its mild conditions and wide scope, thus providing a novel strategy for the sulfonyl radical participating in radical defluorinative coupling.
Topics & Concepts
RadicalSulfonylChemistryCatalysisSurface modificationCombinatorial chemistryTrifluoromethylOrganic chemistryPhysical chemistryAlkylSulfur-Based Synthesis TechniquesRadical Photochemical ReactionsFluorine in Organic Chemistry