<i>Operando</i> Raman and <i>ex situ</i> characterization of an iron-based conductive MOF as a negative electrode in Li-ion batteries
Isabel Ciria‐Ramos, Alex R. Neale, Laurence J. Hardwick, Emilio J. Juárez‐Pérez, Ignacio Gascón, Marta Haro
Abstract
storage. Initially, lithiation occurs primarily at the MOF boundaries, while continuous cycling induces a structural transformation that allows greater accessibility to the inner regions of Fe-HHTP. These results provide a better understanding of the electrochemical and structural behavior of pristine MOFs that allow tailoring their properties for direct application in energy storage devices without the need for high-temperature processes.
Topics & Concepts
Raman spectroscopyElectrodeCharacterization (materials science)In situMaterials scienceElectrical conductorIonChemical engineeringNanotechnologyInorganic chemistryChemistryComposite materialPhysical chemistryOrganic chemistryEngineeringOpticsPhysicsAdvancements in Battery MaterialsSemiconductor materials and devicesGraphene research and applications