2D/2D Heterojunction of BiOBr/BiOI Nanosheets for In Situ H<sub>2</sub>O<sub>2</sub> Production and Activation toward Efficient Photocatalytic Wastewater Treatment
Beverly Qian Ling Low, Wenbin Jiang, Jing Yang, Mingsheng Zhang, Xiao Wu, Hui Zhu, Houjuan Zhu, Jerry Zhi Xiong Heng, Karen Yuanting Tang, Wen‐Ya Wu, Xun Cao, Xue Qi Koh, Casandra Hui Teng Chai, Chui Yu Chan, Qiang Zhu, Michel Bosman, Yong‐Wei Zhang, Ming Zhao, Zibiao Li, Xian Jun Loh, Yujie Xiong, Enyi Ye
Abstract
Abstract The presence of toxic organic pollutants in aquatic environments poses significant threats to human health and global ecosystems. Photocatalysis that enables in situ production and activation of H 2 O 2 presents a promising approach for pollutant removal; however, the processes of H 2 O 2 production and activation potentially compete for active sites and charge carriers on the photocatalyst surface, leading to limited catalytic performance. Herein, a hierarchical 2D/2D heterojunction nanosphere composed of ultrathin BiOBr and BiOI nanosheets (BiOBr/BiOI) is developed by a one‐pot microwave‐assisted synthesis to achieve in situ H 2 O 2 production and activation for efficient photocatalytic wastewater treatment. Various experimental and characterization results reveal that the BiOBr/BiOI heterojunction facilitates efficient electron transfer from BiOBr to BiOI, enabling the one‐step two‐electron O 2 reduction for H 2 O 2 production. Moreover, the ultrathin BiOI provides abundant active sites for H 2 O 2 adsorption, promoting in situ H 2 O 2 activation for •O 2 − generation. As a result, the BiOBr/BiOI hybrid exhibits excellent activity for pollutant degradation with an apparent rate constant of 0.141 min −1 , which is 3.8 and 47.3 times that of pristine BiOBr and BiOI, respectively. This work expands the range of the materials suitable for in situ H 2 O 2 production and activation, paving the way toward sustainable environmental remediation using solar energy.