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High-Performance Solar-Blind Ultraviolet Photodetectors Based on a Ni/β-Ga<sub>2</sub>O<sub>3</sub> Vertical Schottky Barrier Diode

Cizhe Fang, Tongzhou Li, Yao Shao, Yibo Wang, Haodong Hu, Jiayong Yang, Xiangyu Zeng, Xiaoxi Li, Di Wang, Yian Ding, Yan Liu, Yue Hao, Genquan Han

2025Nano Letters40 citationsDOI

Abstract

Ga 2 O 3 Schottky photodiodes are being actively explored for solar-blind ultraviolet (SBUV) detection, owing to the fast photoresponse and easy fabrication. However, their performance, limited by the Schottky contact, mostly underperforms the expectations. Herein, a Ni/β-Ga 2 O 3 vertical Schottky barrier diode (SBD) with an ultrathin anode electrode is demonstrated. Through simple surface treatment, the quality of the Schottky junction is improved, thus the detection performance. The dark current reaches a record of less than 12 fA. Benefiting from this, an ultrahigh photo-to-dark current ratio (PDCR) of 4.92 × 10 7 and specific detectivity D * of 2.76 × 10 15 Jones are achieved. The response time is also reduced to the order of milliseconds. The experimental result shows that the device still works properly at a high temperature of 150 °C. Most importantly, the fabricated photodetectors have good uniformity and operational stability. Our results provide a simple approach to mass produce high-performance Ga 2 O 3 photodetectors, holding tremendous potential for UV imaging applications.

Topics & Concepts

PhotodetectorUltravioletSchottky barrierMaterials scienceOptoelectronicsDiodeSchottky diodeOpticsPhysicsGa2O3 and related materialsZnO doping and propertiesAdvanced Photocatalysis Techniques