Detection of nitrophenols with a fluorescent Zr(<scp>iv</scp>) metal–organic framework functionalized with benzylamino groups
Amina Chatz-Giachia, Athanasia E. Psalti, Anastasia D. Pournara, Manolis J. Manos, Christina Pappa, Konstantinos S. Triantafyllidis, Theodore Lazarides
Abstract
We describe the rational design and synthesis of a fluorescent and π-electron rich Zr(IV) metal-organic framework showing strong emission quenching in the presence of acidic nitroaromatic guests 2,4,6-trinitrophenol and 2,4-dinitrophenol.
Topics & Concepts
FluorescenceQuenching (fluorescence)MetalMetal-organic frameworkMaterials scienceRational designCombinatorial chemistryPhotochemistryOrganic chemistryChemistryNanotechnologyMetallurgyQuantum mechanicsPhysicsAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials