A Pd-Catalyzed Site-Controlled Isomerization of Terminal Olefins
Wenlong Ren, Fei Sun, Jianxiao Chu, Yian Shi
Abstract
An effective Pd-catalyzed isomerization of olefins with 2-PyPPh2 as the ligand is described. A wide variety of trans-2-olefins bearing various functional groups can be obtained with high regio- and stereoselectivity under mild reaction conditions. The ligand is crucial for the reaction.
Topics & Concepts
IsomerizationChemistryStereoselectivityLigand (biochemistry)CatalysisTerminal (telecommunication)Olefin fiberReaction conditionsCombinatorial chemistryMedicinal chemistryStereochemistryOrganic chemistryReceptorBiochemistryTelecommunicationsComputer scienceSynthetic Organic Chemistry MethodsCatalytic Cross-Coupling ReactionsOrganometallic Complex Synthesis and Catalysis