An unprecedented polyoxometalate-encapsulated organo–metallophosphate framework as a highly efficient cocatalyst for CO<sub>2</sub> photoreduction
Zeyu Du, Yingnan Xue, Xiaomei Liu, Ningfang Li, Ji‐Lei Wang, Hua Mei, Yan Xu
Abstract
Both compounds have host organo–metallophosphate (OMPO) frameworks, whereas the Keggin-type POM as a guest encapsulated in this size-matched framework. More interestingly, compound 2 displays outstanding performance in CO 2 photoreduction.
Topics & Concepts
PolyoxometalatePhotocatalysisCatalysisSelectivityChemistryPhotochemistryMaterials scienceCombinatorial chemistryInorganic chemistryOrganic chemistryPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Photocatalysis Techniques